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ZAMAK
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Everything about Zamak totally explained

ZAMAK, also known as ZAMAC, was the trademarked name covering a family of zinc alloys, with a base metal of zinc and alloying elements of aluminum, magnesium and copper. ZAMAK alloys are part of the zinc aluminum alloy family; they're distinguished from the other ZA alloys because of their constant 4% aluminum composition. These alloys are most commonly die cast. ZAMAK avoided this by the use of 99.99% pure zinc metal, produced by New Jersey's use of a refluxer as part of the smelting process.
   ZAMAK can be electroplated, wet painted, and chromate conversion coated well.

Standards

Zinc alloy chemical composition standards are defined per country by the standard listed below:
Country Zinc ingot Zinc casting
Europe EN1774 EN12844
USA ASTM B240 ASTM B86
Japan JIS H2201 JIS H5301
Australia AS 1881 - SAA H63 AS 1881 - SAA H64
China GB 8738-88 -
Canada CSA HZ3 CSA HZ11
International ISO 301 -
ZAMAK goes by many different names based on standard and/or country:
Traditional name Short composition name Form Common ASTM Short European designation JIS China UK BS 1004 France NFA 55-010
or
Kirksite
ZnAl4Cu3 - ZX04 - Z35541 ZX01 - Z33520 Ingot Used in Asia only ZA-4, ZN-004 It later gained popularity for making short run injection molding dies.
Property Metric value English value
Mechanical properties
Ultimate tensile strength 397 MPa (331 MPa aged) 58,000 psi
Yield strength (0.2% offset) 361 MPa 52,000 psi
Impact strength 38 J (7 J aged) 28 ft-lbf (5 ft-lbf aged)
Elongation at Fmax 3% (2% aged)
Elongation at fracture 6%
Shear strength 317 MPa 46,000 psi
Compressive yield strength 641 MPa 93,000 psi
Fatigue strength (reverse bending 5x108 cycles) 59 MPa 8,600 psi
Hardness 130 Brinell (98 Brinell aged)
Modulus of elasticity 96 GPa 14,000,000 psi
Physical properties
Solidification range (melting range) 379—390 °C 714—734 °F
Density 6.8 kg/dm3 0.25 lb/in3
Coefficient of thermal expansion 27.8 μm/m-°C 15.4 μin/in-°F
Thermal conductivity 105 W/m-K 729 BTU-in/hr-ft2-°F
Electrical resistivity 6.85 μΩ-cm at 20 °C 2.70 μΩ-in at 68 °F
Latent heat (heat of fusion) 110 J/g 4.7x10-5 BTU/lb
Specific heat capacity 419 J/kg-°C 0.100 BTU/lb-°F
Coefficient of friction 0.08

KS

The KS alloy was developed for spin casting decorative parts. It has the same composition as ZAMAK 2, except with more magnesium in order to produce finer grains and reduce the orange peel effect. |- ! Property ! Metric value ! English value |- ! colspan=3| Mechanical properties |- | Ultimate tensile strength | < 200 MPa | < 29,000 psi |- | Yield strength (0.2% offset) | < 200 MPa | < 29,000 psi |- | Elongation | colspan=2 align="center"| < 2% |- | Hardness | colspan=2 align="center"| 150 Brinell max |- ! colspan=3| Physical properties |- | Solidification range (melting range) | 380—390 °C | 716—734 °F |- | Density | 6.6 g/cm3 | 0.25 lb/in3 |- | Coefficient of thermal expansion | 28.0 μm/m-°C | 15.4 μin/in-°F |- | Thermal conductivity | 105 W/m-K | 729 BTU-in/hr-ft2-°F |- | Electrical conductivity | colspan=2 align="center"| 25% IACS |- | Specific heat capacity | 419 J/kg-°C | 0.100 BTU/lb-°F |- | Coefficient of friction | colspan=2 align="center"| 0.08 |}

ZAMAK 3

ZAMAK 3 is the de facto standard for the ZAMAK series of zinc alloys; all other zinc alloys are compared to this. ZAMAK 3 has the base composition for the ZAMAK alloys (96% zinc, 4% aluminum). It has excellent castablity and long term dimensional stability. More than 70% of all North American zinc die castings are made from ZAMAK 3. (Ingot) | min | 3.9 | - | 0.025 | - | - | - | - | - | - | - | - |- | max | 4.3 | 0.1 | 0.05 | 0.004 | 0.003 | 0.002 | 0.075 | - | - | - | - |- | rowspan=2|ASTM B86 (Cast) | min | 3.5 | - | 0.025 | - | - | - | - | - | - | - | - |- | max | 4.3 | 0.25 | 0.05 | 0.005 | 0.004 | 0.003 | 0.1 | - | - | - | - |- | rowspan=2|EN1774 (Ingot) | min | 3.8 | - | 0.035 | - | - | - | - | - | - | - | - |- | max | 4.2 | 0.03 | 0.06 | 0.003 | 0.003 | 0.001 | 0.02 | 0.001 | 0.02 | - | - |- | rowspan=2|EN12844 (Cast) | min | 3.7 | - | 0.025 | - | - | - | - | - | - | - | - |- | max | 4.3 | 0.1 | 0.06 | 0.005 | 0.005 | 0.002 | 0.05 | 0.02 | 0.03 | - | - |- | rowspan=2|JIS H2201 | min | 3.9 | - | 0.04 | - | - | - | - | - | - | - | - |- | max | 4.3 | 0.03 | 0.06 | 0.003 | 0.003 | 0.001 | 0.05 | - | 0.001 | 0.0005 | 0.001 |- | rowspan=2|GB8738-88 | min | 3.9 | - | 0.03 | - | - | - | - | - | - | - | - |- | max | 4.3 | 0.1 | 0.06 | 0.004 | 0.003 | 0.0015 | 0.035 | - | - | - | - |- | colspan=13| Impurity |}
Property Metric value English value
Mechanical properties
Ultimate tensile strength 208 MPa 30,200 psi
Yield strength (0.2% offset) 268 MPa 38,900 psi
Impact strength 46 J (56 J aged) 34 ft-lbf (41 ft-lbf aged)
Elongation at Fmax 3%
Elongation at fracture 6.3% (16% aged)
Shear strength 214 MPa 31,000 psi
Compressive yield strength 414 MPa 60,000 psi
Fatigue strength (reverse bending 5x108 cycles) 48 MPa 7,000 psi
Hardness 97 Brinell
Modulus of elasticity 96 GPa 14,000,000 psi
Physical properties
Solidification range (melting range) 381—387 °C 718—729 °F
Density 6.7 g/cm3 0.24 lb/in3
Coefficient of thermal expansion 27.4 μm/m-°C 15.2 μin/in-°F
Thermal conductivity 113 W/mK 784 BTU-in/hr-ft2-°F
Electrical resistivity 6.37 μΩ-cm at 20 °C 2.51 μΩ-in at 68 °F
Latent heat (heat of fussion) 110 J/g 4.7x10-5 BTU/lb
Specific heat capacity 419 J/kg-°C 0.100 BTU/lb-°F
Coefficient of friction 0.07

ZAMAK 4

ZAMAK 4 was developed for the Asian markets to reduce the effects of die soldering while maintaining the ductility of ZAMAK 3. This was achieved by using half the amount of copper from the ZAMAK 5 composition.
Alloying elements Impurities
Standard Limit Al Cu Mg Pb Cd Sn Fe Ni Si In Tl
Ningbo Jinyi Alloy Material Co. min 3.9 0.3 0.03 - - - - - - - -
max 4.3 0.5 0.06 0.003 0.002 0.002 0.075 - - - -
Genesis Alloys Ltd. min 3.9 0.3 0.04 - - - - - - - -
max 4.2 0.4 0.05 0.003 0.002 0.001 0.02 0.001 0.02 0.0005 0.001
Property Metric value English value
Mechanical properties
Ultimate tensile strength 317 MPa 46,000 psi
Yield strength (0.2% offset) 221—269 MPa 32,000—39,000 psi
Impact strength 61 J (7 J aged) 45 ft-lbf (5 ft-lbf aged)
Elongation 7%
Shear strength 214—262 MPa 31,000—38,000 psi
Compressive yield strength 414—600 MPa 60,000—87,000 psi
Fatigue strength (rotary bending 5x108 cycles) 48—57 MPa 7,000—8,300 psi
Hardness 91 Brinell
Physical properties
Solidification range (melting range) 380—386 °C 716—727 °F
Density 6.6 g/cm3 0.24 lb/in3
Coefficient of thermal expansion 27.4 μm/m-°C 15.2 μin/in-°F
Thermal conductivity 108.9—113.0 W/m-K @ 100 °C 755.6—784.0 BTU-in/hr-ft2-°F @ 212 °F
Electrical conductivity 26-27% IACS
Specific heat capacity 418.7 J/kg-°C 0.100 BTU/lb-°F

ZAMAK 5

ZAMAK 5 has the same composition as ZAMAK 3 with the addition of 1% copper in order to increase strength (by approximately 10% |- ! Property ! Metric value ! English value |- ! colspan=3| Mechanical properties |- | Ultimate tensile strength | 331 MPa (270 MPa aged) | 48,000 psi (39,000 psi aged) |- | Yield strength (0.2% offset) | 295 MPa | 43,000 psi |- | Impact strength | 52 J (56 J aged) | 38 ft-lbf (41 ft-lbf aged) |- | Elongation at Fmax | colspan=2 align="center"| 2% |- | Elongation at fracture | colspan=2 align="center"| 3.6% (13% aged) |- | Shear strength | 262 MPa | 38,000 psi |- | Compressive yield strength | 600 MPa | 87,000 psi |- | Fatigue strength (reverse bending 5x108 cycles) | 57 MPa | 8,300 psi |- | Hardness | colspan=2 align="center"| 114 Brinell |- | Modulus of elasticity | 96 GPa | 14,000,000 psi |- ! colspan=3| Physical properties |- | Solidification range (melting range) | 380—386 °C | 716—727 °F |- | Density | 6.7 kg/dm3 | 0.24 lb/in3 |- | Coefficient of thermal expansion | 27.4 μm/m-°C | 15.2 μin/in-°F |- | Thermal conductivity | 109 W/mK | 756 BTU-in/hr-ft2-°F |- | Electrical resistivity | 6.54 μΩ-cm at 20 °C | 2.57 μΩ-in at 68 °F |- | Latent heat (heat of fusion) | 110 J/g | 4.7x10-5 BTU/lb |- | Specific heat capacity | 419 J/kg-°C | 0.100 BTU/lb-°F |- | Coefficient of friction | colspan=2 align="center"| 0.08 |}

ZAMAK 7

ZAMAK 7 has less magnesium than ZAMAK 3 to increase fluidity and ductility, which is especially useful when casting thin wall components. In order to reduce inter-granular corrosion a small amount of nickel is added and impurities are more strictly controlled. |- ! Property ! Metric value ! English value |- ! colspan=3| Mechanical properties |- | Ultimate tensile strength | 285 MPa | 41,300 psi |- | Yield strength (0.2% offset) | 285 MPa | 41,300 psi |- | Impact strength | 58.0 J | 42.8 ft-lbf |- | Elongation at fracture | colspan=2 align="center"| 14% |- | Shear strength | 214 MPa | 31,000 psi |- | Compressive yield strength | 414 MPa | 60,000 psi |- | Fatigue strength (reverse bending 5x108 cycles) | 47.0 MPa | 6,820 psi |- | Hardness | colspan=2 align="center"| 80 Brinell |- ! colspan=3| Physical properties |- | Solidification range (melting range) | 381—387 °C | 718—729 °F |- | Coefficient of thermal expansion | 27.4 μm/m-°C | 15.2 μin/in-°F |- | Thermal conductivity | 113 W/m-K | 784 BTU-in/hr-ft2-°F |- | Electrical resistivity | 6.4 μΩ-cm | 2.5 μΩ-in |- | Specific heat capacity | 419 J/kg-°C | 0.100 BTU/lb-°F |- | Casting temperature | 395—425 °C | 743—797 °F |}

Uses

Common uses for ZAMAK alloys include:
  • Blenders
  • Mirror frames
  • Plumbing fittings
  • Zippers
  • Bathroom fixtures (faucets and shower heads)
  • Staplers
  • Handles
  • Locks
  • Die-cast toys
  • Automotive parts
  • Ceiling fans
  • Golf clubs
  • Fishing reels
  • Wheel balancing weights (especially prominent in the European Union)Further Information

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